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9780471973720

Enantiocontrolled Synthesis of Fluoro-Organic Compounds Stereochemical Challenges and Biomedical Targets

by
  • ISBN13:

    9780471973720

  • ISBN10:

    0471973726

  • Edition: 1st
  • Format: Hardcover
  • Copyright: 1999-07-09
  • Publisher: WILEY

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Summary

Written by a leading expert in the field, this is a comprehensive review of the methods for preparing stereochemically defined fluorine-containing compounds of biomedical importance. Fluorinated organic compounds are well known for their unusual reactivity but the growing importance of these compounds in the biomedical field has been accompanied by an increasing awareness of the necessity to synthesise and explore the biological properties of stereochemically defined fluoro-compounds. This is the first book written on this exciting area of research. It contains: * detailed reviews on stereocontrolled synthesis of biologically important compounds * 21 chapters covering the main areas of asymmetric synthesis and biocatalysts where fluorine plays a key role * mechanisms and methods for synthesizing fluoro-organic compounds Written for professionals involved in organic, physical and organofluorine chemistry, natural product synthesis, biological, pharmaceutical and other life science related industries.

Author Biography

Vadim A. Soloshonok is the editor of Enantiocontrolled Synthesis of Fluoro-Organic Compounds: Stereochemical Challenges and Biomedical Targets, published by Wiley.

Table of Contents

List of Contributors
vii
Preface xi
Foreword xv
Asymmetric Fluorination
1(32)
F.A. Davis
H. Qi
G. Sundarababu
Asymmetric Fluoroalkylation
33(30)
K. Iseki
Synthesis of Stereochemically Defined Fluoro-Organic Compounds via Dehydroxy-Fluorination and Related Reactions
63(44)
R.L. Gree
J.-P. Lellouche
Asymmetric Synthesis of Fluoro-Organic Compounds via Chiral Sulfoxide Chemistry
107(54)
P Bravo
M. Zanda
Synthesis of Stereochemically Defined Trifluoromethyl-Containing Compounds from (S)-3,3,3-Trifluoropropene Oxide
161(18)
T. Katagiri
Asymmetric Reduction of Fluorine-Containing Carbonyl Compounds
179(50)
P.V. Ramachandran
H.C. Brown
Asymmetric Aldol Reactions of Fluoro-Carbonyl Compounds
229(34)
V.A. Soloshonok
Asymmetric Michael Addition Reactions of Fluorocarbons
263(24)
T. Yamazaki
Asymmetric Oxidation of Fluoro-Olefins
287(20)
T. One
Biocatalytic Approaches to Enantiomerically Enriched Fluoro-Organic Compounds
307(42)
T. Fujisawa
M. Shimizu
Stereocontrolled Syntheses of Fluorinated Carbohydrates
349(42)
B. Novo
G. Resnati
Asymmetric Synthesis of Fluoro-Amino Acids
391(28)
K. Uneyama
Chiral Non-racemic Fluorinated Nucleosides: Recent Synthetic Methods
419(32)
F. Viani
Asymmetric Syntheses and Resolutions of Fluorinated Volatile Anesthetics
451(18)
K. Ramig
D.F. Halpern
Fluorine-Containing Chiral Auxiliaries and Ligands for General Asymmetric Synthesis
469(28)
T. Kubota
Fluorine-Containing Agents for Determining Enantiomeric Excess of Chiral Molecules
497(38)
Y. Takeuchi
T. Takahashi
Fluorine-Containing Chiral Liquid Crystals: Syntheses and Properties
535(22)
T. Kusumoto
T. Hiyama
Synthesis of Enantiopure α-Trifluoromethyl Alcohols via Chiral Lewis Acid-Catalyzed Carbonyl-Ene Reactions and their Application in the Design of New Liquid Crystals
557(18)
K. Mikami
T. Yajima
Coordination Ability of Fluorine to Proton or Metals Based on Experimental and Theoretical Evidence
575(26)
T. Yamazaki
T. Kitazume
Physical and Structural Size of Fluorine in Fluoro-Organic Compounds
601(12)
C.G. Beguin
The Chemical and Physiological Size of Fluorine
613(48)
M. Schlosser
Index 661

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